 Preparation for controlling growth of grain cereals
专利摘要:
MEANS FOR REGULATING GROWTH OF GRAIN CEREALS, containing 2-chloroethylphosphonic acid, characterized in that, in order to increase the yield of plants, it additionally contains M, K-dimethylpiperidinium chloride in the following ratio of ingredients, wt..ch .: 2-Chloroethylphosphonic acid 1 N, Ы -Dimethylpiperidinium1-3, 8 C 9 公开号:SU1111674A3 申请号:SU782701455 申请日:1978-12-14 公开日:1984-08-30 发明作者:Петер Шотт Эберхард；Ланг Ханс 申请人:Басф Аг (Фирма)； IPC主号:
专利说明:
The invention relates to agriculture, namely to means for regulating the growth of plants, containing a mixture of active principles. A plant growth regulator based on N ,, N-dimetypipercincinium chloride G13 is known. It is also known an agent for regulating the growth of cereals, containing 2-chloroethylphosphonic acid 2. However, known agents do not sufficiently provide an increase in the yield of plants. The purpose of the invention is to increase the yield of cereals. The goal is achieved by the fact that the agent for regulating and growth of cereals, containing 2-chloroethylphosphonic acid, additionally contains N, N-dimethylpiperidinium chloride, with the following ratio of ingredients, wt. H .: 2-Chloroethylphosphogycic acid1 N, N-Dnmetilpiperidinium chloride 1 3.8 HoBF) ie mixtures, in particular, have a synergistic effect on cereals, i.e. the effect of the mixture exceeds that of the individual active principles. In addition, the mixtures have better compatibility with plants than the known means and lead to improved stems stability in cereals, so that they are observed with reduced lodging of plants. In particular, mixtures of N, N-dimethylpyridine chloride with 2-chloroethylphosphonic acid have a good growth regulating effect. You can mix the active beginning in a wide range, for example (1: 1) - (1: 3.8) weight, h. The application occurs, for example, in the form of directly spraying solutions, powders, highly concentrated, oily or other suspensions or dispersions of emulsions, oil dispersions, dust pastes, soil preparation agents, granules by spraying, dusting, spraying or watering. The forms of application depend completely from the purpose of the application, in any case they should ensure the smallest possible distribution of the active principles of the invention. For the manufacture of directly sprayed solutions, emulsions, pastes and oil dispersions, mineral fractions of medium to high boiling points, such as kerosene or diesel oil, then coal tar oil, etc. are used. and plant or animal casts, aliphatic, cyclic, and aromatic hydrocarbons, for example, benzene, toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes, or their derivatives, for example, methanol, ethanol, propanol, butanol, floroform, carbon tetrachloride, cyclohexane, ethanol, propanol, butanol, floroform, tetrahydronaphthalene, cyclohexane, and methanol, naphthalene. isophorone, etc., highly polar solvents such as dimethylformamide, dimethyl sulfoxide, N-methylpyrlydone, water, etc. Aqueous use forms can be obtained from emulsion concentrates, pastes or wetted Powders, oil dispersions are added by adding water. To form emulsions, pastes or oil dispersions, substances, as such, either dissolved in an oil or in a solvent, can be homogenized by means of adhesives, wetting agents, dispersants or emulsifiers in water. However, it is also possible to obtain concentrates consisting of active ingredient, wetting agent, adhesive, dispersant or emulsifier and, if appropriate, a solvent or oil, which are suitable. Diluted with water. As surface-active substances, you should specify: salts with alkaline or alkaline earth metals or ammonium ligninsulfonic acid, naphthalenesulfonic acids, phenolsulfonic acids, alkylarylsulfonates, alkyl sulfates, alkyl sulfonates, salts with alkali and alkaline-earth metals dibut ilnaphthalenesulfonic acid, lauryl ether sulfate, fatty alcohol sulfates, alkali metal and alkaline earth metal fatty acid salts, sulfated hexadecanols salts, heptadecanols, octadecanols, sulfated glycol ether salts of fatty alcohol, sulfonated naphthalene and to the chart, and to a graph; condensation of naphthalene or naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octyl phenol ether, ethoxylated isoylphenol, octyl phenol, nonylpolyne spent sulphite liquors and methylcellulose. Powders, soil aids and dusts can be obtained by mixing or co-milling the active principles with a solid carrier. The pellets, for example, coated, impregnated and homogeneous, can be obtained by binding the active principles with solid carriers. Solid carriers are, for example, mineral lands, for example silica gel, silicic acids, silica gels, silicates, talc, kaolin, attacli, limestone, lime, chalk talc, bolus, loess, clay, dolomite, diatomaceous earth, calcium sulfate and magnesium, magnesium oxide, ground plastics fertilizers, such as ammonium sulfate, ammonium phosphate, ammonium nitrate, chevins, and plant products, such as bread flour (different varieties), bark flour, wood flour from hazelnut powder, cellulose powder, and other solid carriers . Aqueous formulations contain 30–70 times the weight of the active ingredient. PRI me R 1, Spring chaff of the Villa variety is treated with aqueous solutions of active ingredients 74 days after sowing. 101 days after planting, plant height is measured (average is obtained from every 100 measurements). Plant resistance to lodging is assessed 124 days after sowing, and 1 is the best value, after which resistance drops to 9, 4to means the lack of resistance (Table 1). In terms of decreasing plant height, Example 1 confirms the synergistic effect of mixtures, in contrast to individual components. PRI M me r 2. Winter chmen varieties Birgit process, aqueous solutions of active principles began 219 days after sowing. Harvesting 281 days after sowing. The results are shown in Table. 2. Example 2 also proves the synergistic effect of the mixture in contrast to the individual components. PRI me R 3. Demolished varieties Flamingskrone treated with aqueous solutions of active principles began 72 days after sowing. Stability is determined 131 days after sowing (Table 3). And under conditions of stronger lodging of untreated plants, the mixture leads to a synergistic improvement in resistance. PRI me R 4. Oats Borrus varieties are treated with aqueous solutions of active principles 80 days after sowing. Measurement of plant growth 105 days after sowing. Harvesting after 4 months. after sowing (tab. 4). The results of this experiment clearly show that the synergistic effect of the mixture exceeds that of the individual components. PRI me R 5. Winter rye varieties Carocurz is treated with aqueous solutions of active principles 196 days after sowing. Measurement of plant height 235 days after sowing (Table 5). Like other grains, the mixture in this case causes synergies. cuts in plant growth. Example 6. Winter rye varieties Kustro treated with aqueous solutions of active principles began 290 days after sowing. Harvesting 282 days after sowing (Table 6). Using the example of this winter rye variety, a good effect of the mixture (in a ratio of just 3: 1) on harvesting is proved. PRI me R 7. Corn Limac varieties are treated with aqueous solutions of the effect of lean began 60 days after sowing. Measurement of plant growth 90 days after sowing. Harvest is estimated 167 days after sowing (Table 7). The blend has a synergistic effect compared to the respective individual components in terms of growth reduction and relatively cocking. Unwanted plant growth is reduced in favor of increased yields. PRI me R 8 “Winter chmeny varieties of the Mirra variety are treated with aquatic disinfectants of active principles 200 days after sowing. Measurement of plant growth 227 days after sowing. Resilience is determined 270 days after sowing (Table 8). Regarding reduced growth and improved stability, the mixture has a synergistic effect compared to the individual components. PRI me R 9 Winter chmeny varieties Ogra are treated with aqueous solutions of active principles 213 n-s after sowing. Evaluation of plant height and resistance was made 232 and 288 days after sowing, respectively. Harvest is assessed 244 days after sowing (Table 9). And this mixture has a synergistic effect compared with the individual components. The height of the solution of the scientific research institute, stability and productivity improve noticeably. PRI me 10. The winter chmen osta dura is treated with aqueous solutions of the active principles 124 days after sowing. Harvest is estimated 185 days after sowing (Table 10). In this example, clearly shows the high yield increase achieved with the help of a mixture. Example 11. Spring rye Beacon varieties are treated with water. solutions of active principles after 59 days after sowing. Plant height is measured 100 days after sowing (Table 11). The example shows that by combining the components 4: 1 a synergistic effect is achieved compared with the individual components. Example 12. Spring rye Kustro litter is treated with water astorins 204 days after sowing. The height is determined after 232 days, and the harvest is done 285 days after sowing (Table 12). Reducing plant growth and by. yield shows a clearly superior effect of the mixture (DPH + + HEFC) compared with the known salt A, where A is N, N-dimethylpiperidinium salt of 2-chlorotane phosphonic o acid (known from the calculations of the Federal Republic of Germany 2422807). Example 13. Winter rye is treated with aqueous solutions of active principles 206 days after 5 sowing. Sustainability was assessed after 261 days, and harvesting — 288 days after sowing (Table 13). And in this case, the mixture of DPH + HEPC clearly exceeds salt A in relation to the improvement of stability and increase in yield. Example 14 Spring rye varieties Somro are treated with water. 5 solutions 85 days after sowing. The plant height was measured after 100 days, and the harvest was done 153 days after sowing (Table 14). A reduction in growth and an increase in yields, in this case, prove the superior effect of the mixture of DPH + HEFC before salt A, where A is N, H-dimethylpiperidinium salt of 2-chloroethanephosphonic acid. Example 15. Winter barley 5 Ago varieties are treated with aqueous solutions of active principles 208 days after sowing. The assessment is stable. in 271 days, the harvest is carried out in 279 days 0 after sowing (table. 15). Thus, the treatment with the proposed mixture leads, comparatively 5 with salt A, to significantly greater stability and, due to better compatibility with plants, to a significant increase in yield. Table 1 Untreated control DPH HEFK dph + HEFK dph + HEFK DPH — H, K-dimethylpiperidinium chloride; X HEFC - 2-chloroethylphosphonic acid. table 2 o72, 4 b 920 72.5 442 78.3 920 80.0 + 442 3.5 1.0 2.5 2.1 2.5 A.7 1.0 8.1 2.5 9.1 Table 3 Untreated 7.0 control 45 0.3 460 6.7 DPH 7.0 221 O HEFK 460 50 DPH + 6.3 0.7 + 221 HEFC 1111674 .Table 4 94.0. 90, 2 920 89.3 960 920 78.0 480 .Table 7 Table 8 6.5 2.5 4.0 3.8 2.0 4.5 4.7 5.0 1.5 16,0 129.0 126.4 2.6 920 127.7 1.3 480 920 o122, 6 6.4 480 N, N-Dimethylamide-2-chlorophosphonic acids DPH + , N, N-Dimethylamide 2-chlorophosphonic acid Table 9 58.1,100 4.0 0.3 57.5 99 3.7 1,3 59,5 102 2.7 2.7 60.9 105 1,3 Table 10 49.1 103 53.7 113 1380 915 + 465 + HEFK T a o l and c a 11 Table 12 Table 13 3.8 3.0. 54,6103 4,556,4106 2.3 17 I 1P674 18 Table 14
权利要求:
Claims (2) [1] Means for regulating the growth of cereals containing 2-chloroethylphosphonic acid, characterized in that, in order to increase the yield of plants, it additionally contains N, N-dimethylpiperidinium chloride in the following ratio of ingredients, wt.h .: [2] 2-Chloroethylphosphonic acid 1 Ν, Ν-Dimethylpiperidinium chloride 1-3.8. · <□ S9 (L s 4 ^ 1 '111
类似技术:
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同族专利:
公开号 | 公开日 NO148137B|1983-05-09| FR2411564A1|1979-07-13| US4447255A|1984-05-08| DK561378A|1979-06-16| DE2755940A1|1979-06-21| FI61787B|1982-06-30| HU184602B|1984-09-28| RO75106A|1980-09-30| SE446495B|1986-09-22| JPS5486621A|1979-07-10| IT1101521B|1985-10-07| CH638374A5|1983-09-30| DE2755940C2|1986-01-02| IL56024D0|1979-01-31| PL211704A1|1979-07-30| FI61787C|1982-10-11| ZA787034B|1979-12-27| ATA893678A|1980-07-15| SE7812746L|1979-06-16| IE782468L|1979-06-15| NO148137C|1983-08-17| NO783955L|1979-06-18| AR222981A1|1981-07-15| GR65602B|1980-10-14| DD140534A5|1980-03-12| BG33271A3|1983-01-14| NL7812035A|1979-06-19| IL56024A|1982-01-31| NL189442B|1992-11-16| AU4228978A|1979-06-21| FR2411564B1|1984-08-03| JPH0219085B2|1990-04-27| DK156688C|1990-03-05| IE47690B1|1984-05-30| GB1597686A|1981-09-09| BR7808232A|1979-08-14| PL109486B2|1980-06-30| IT7830528D0|1978-12-04| DK156688B|1989-09-25| AU522162B2|1982-05-20| TR20696A|1982-05-11| BE872682A|1979-06-12| CS212314B2|1982-03-26| FI783598A|1979-06-16| LU80649A1|1979-04-13| AT361018B|1981-02-10| CA1122810A|1982-05-04| NL189442C|1993-04-16|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 BE795534A|1972-02-18|1973-08-16|Basf Ag|AGENTS FOR REGULATING PLANT GROWTH, CONTAINING NITROGEN SALT AS ACTIVE INGREDIENT| JPS4966832A|1972-10-24|1974-06-28| DE2361410A1|1973-12-10|1975-06-19|Basf Ag|GROWTH REGULATORY AGENTS| DE2422807C3|1974-05-10|1979-05-23|Basf Ag, 6700 Ludwigshafen|Salts of phosphonic acids| JPS5295612A|1976-02-05|1977-08-11|Basf Ag|Phosphonic acid salts| DE2609105A1|1976-03-05|1977-09-15|Basf Ag|AMMONIUM AND SULPHONIUM SALTS|FR2460111B2|1979-06-29|1985-06-21|Gaf Corp|COMPOSITION BASED ON AN AQUEOUS MIXTURE OF N-METHYL-2-PYRROLIDONE AND 2-HALOGENETHYLPHOSPHONIC ACID AND ITS APPLICATION TO THE TREATMENT OF PLANTS| DE3007224A1|1980-02-27|1981-09-10|Basf Ag, 6700 Ludwigshafen|METHOD FOR REGULATING THE GROWTH OF PLANTS| HU192890B|1984-09-21|1987-07-28|Borsodi Vegyi Komb|Plant growth regulating composition containing 3-iso-nonyl-oxy-propyl-ammonium-methyl-phosphonate as active ingredient| IL77243A|1984-12-21|1996-11-14|Procter & Gamble|Pharmaceutical compositions containing geminal diphosphonic acid compounds and certain such novel compounds| DE3709806A1|1987-03-25|1988-10-06|Basf Ag|AGENTS FOR REGULATING PLANT GROWTH| US5668085A|1987-04-29|1997-09-16|Monsanto Company|Glyphosate formulations comprising alkoxylated amine surfactants| EP0535415A1|1991-10-04|1993-04-07|Basf Corporation|Plant growth regulator compositions| JP2815081B2|1993-02-18|1998-10-27|矢崎総業株式会社|Connector device for connection between batteries| US6288009B1|1998-04-10|2001-09-11|Basf Corporation|Plant growth regulator compositions| US20060229208A1†|2003-08-08|2006-10-12|Basf Aktiengesellschaft|Use of acyl cyclohexandione derivatives in conjunction with ethephon for treating pomaceous fruit| DE102005062269A1|2005-12-24|2007-06-28|Bayer Materialscience Ag|New castor oil-based polyol emulsions|
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申请号 | 申请日 | 专利标题 DE2755940A|DE2755940C2|1977-12-15|1977-12-15|Means for regulating plant growth| 相关专利
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